When was the combined gas law discovered




















These laws explained interesting effects such as why beer kegs and soda cans can explode under certain conditions. They were discovered by holding any of the variables pressure, temperature , or volume, constant with respect to the other two. Clapeyron is one of the founding fathers of thermodynamics ; he was the one who gave wide exposure to the little known work of Sadi Carnot , and he had a profound influence on Lord Kelvin and Clausius.

The Clausius-Clapeyron equation, which describes the slope of phase boundary lines such as those between a liquid and gas, is named after him. The ideal gas law is an equation of state that is very important and fundamental in thermodynamics. It is found by combining the laws of Boyle, Charles, and Gay-Lussac, into one elegant equation as follows below. Robert Boyle — investigates the relationship between the volume of a fixed mass of gas, at constant temperature, and the pressure acting on it.

He discovers that pressure is inversely proportional to volume. Guillaume Amontons — investigates the relationship between the pressure of a gas and its temperature. He discovers that, over the range from freezing to boiling water, the pressure increases by about one-third. Daniel Gabriel Fahrenheit — designs a mercury-in-glass thermometer and develops a temperature scale now named after him. Anders Celsius — develops a new temperature scale based on the freezing and boiling points of water.

A year after his death, the scale is reversed to make it more practical. James Six — invents a thermometer that allows maximum and minimum temperatures to be measured over a given time period. It proves to be most useful to meteorologists, and the basic design still remains in use today. With the recent development of accurate thermometers, Jacques Charles — is able to investigate the relationship between the volume of a gas and its temperature.

He is the first to observe that the pressure of a mixture of gases is the sum of the pressures of the various gases in the mixture. William Henry — discovers that the solubility of a gas in a liquid is directly proportional to the gas pressure. The idea is the same as the others. Double the number of atoms and you double the volume. The only way to combine these four laws was if the pressure times the volume divided by the temperature and number of atoms were a constant.

That means that if the pressure and volume were increased times two, the temperature would need to be increased by four, or the number of atoms would have to change. That constant on the right-hand side has a name and a symbol.

P, V, and T are the pressure, volume, and temperature; R is the ideal gas constant; n is the number of gas molecules in volume in a funny unit. No, it has nothing to do with the nearsighted underground rodent. The term comes from an abbreviation of the German word for molecule. A mole is basically like the word dozen. You could have a dozen eggs or a dozen pairs of shoes. Similarly, you could have a mole of molecules. In any event, the symbol n is just the number of molecules of gas you have, divided by that 6 times 10 to the 23rd number.

That tells you the amount of molecules you have in units of moles. It states that the ratio of the product of pressure and volume and the absolute temperature of a gas is equal to a constant. R is represented by a universal gas constant. The value of R depends upon the units but is usually displayed in S.



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